The triflate group refers to a chemical group that is commonly used in synthetic organic chemistry as a leaving group due to its high effectiveness. It is known for its thermal stability and electron …

Jul 7, 2011 · One triflate in molybdenum imido alkylidene NHC bistriflate complexes can be replaced by tetraphenylborate (BPh4−), tetrakis (3,5-trifluoromethylphenyl) borate (BAr F4−), …

Jan 1, 2007 · Trifluoromethanesulfonate (triflate; CF 3 SO 3 -; TfO −) has long been believed as a classical “non-coordinating” anion, and in fact, many transition metal triflates act as a cationic …

Sep 9, 2012 · This review details the current methods used to prepare vinyl triflates derived from 1,3-dicarbonyl compounds and describes the reactivity of such fun…

Jan 1, 1981 · Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media. The …

Jul 8, 2012 · We have demonstrated that iron (III) triflate was a new efficient catalyst for Type I Ferrier Rearrangement. By use of this catalyst, a series of alcohols was reacted with glucal …

Oct 30, 2023 · The triflate group at nitrogen imparts stability to an otherwise unstable amine, amide, or sulfonamide derivatives of different type. The review summarizes recent trends in …

Oct 1, 2023 · In conclusion, we have developed a novel and useful method by using a ytterbium (III) triflate synthesis strategy to pyrrolidine derivatives from ketoximes bearing different …

Among these, rare‐earth triflates have garnered attention due to their water compatibility, environmental friendliness, noncorrosive nature, and reusability. In particular, scandium (III) …

May 12, 2000 · The reaction of triflic anhydride with carbonyl compounds consists of the electrophilic attack of the anhydride on the carbonyl oxygen, resulting in the formation of the …