Nitroxide-mediated radical polymerization is a method of radical polymerization that makes use of an nitroxide initiator to generate polymers with well controlled stereochemistry and a very low …

N-Methyl-2-pyrrolidone (NMP) is an organic compound consisting of a 5-membered lactam. It is a colorless liquid, although impure samples can appear yellow. It is miscible with water and with …

Nov 16, 2020 · This review will summarize the progress made in the diversity of monomers polymerizable by NMP and an outlook of the ability of NMP to polymerize new families of …

Nitroxide-mediated radical polymerization (NMP) is a controlled radical polymerization (CRP) technique that relies on the reversible capture of the propagating species by nitroxides with …

Nitroxide-mediated radical polymerization (NMP) is one of the most common CRP techniques that employs reversible thermal homolysis of C–ON bond of an alkoxyamine to produce an …

Dec 1, 2016 · NMP remains the best RDRP technique for the controlled polymerization of styrene and functionalized styrene monomers but presents some monomer restrictions. This difficulty …

NMP stands out due to its simplicity: the polymerization is thermally initiated in the absence of an external radical source or a metal catalyst. NMP involves a combination of radical initiator (Ι), …

Apr 2, 2023 · A mathematical model for polymerization kinetics and molar mass development in the nitroxide-mediated polymerization (NMP) of vinyl monomers in supercritical carbon dioxide …

May 13, 2021 · Nitroxide-mediated polymerization (NMP) has emerged as a technique able to control the polymerization of a wide range of monomers and to allow the formation of block …

Recent reports have shown promising possibilities for methacrylate homopolymerizations. This review will summarize the progress made in the diversity of monomers polymerizable by NMP …