
Reaction molecularity and order - Chemistry Stack Exchange
The molecularity of an elementary reaction is the number of molecules coming together to react in an elementary reaction.It is most important to distinguish molecularity from order: reaction …
physical chemistry - What is the difference between Molecularity …
Sep 27, 2014 · In fact, molecularity and order of reaction are identical if the reaction is elementary. They may become different when the reaction is complex and has a mechanism. …
Relationship between molecularity and the reaction order
Jan 24, 2021 · Molecularity applies to single elementary reaction steps and is seldom higher than 2. The reaction order is the "effective molecularity" of the whole set of linked reactions, if it had …
Why can't the molecularity be determined from the rate law?
The coefficients only correspond to the rate law coefficients if the reaction is elementary. Elementary reactions are ones where the reagent(s) combine through a mechanism implied by …
Why doesn't molecularity ever exceed 3? - Chemistry Stack Exchange
Jun 21, 2022 · Recently, I learnt that molecularity of a reaction is limited to 3 and even that is quite rare. I searched online and asked my teacher about this but the explanation given was that it is …
physical chemistry - What is the molecularity of the RDS of a zero ...
Jun 26, 2018 · Molecularity - The [integer] number of reactant molecular entities that are involved in the 'microscopic chemical event' constituting an elementary reaction. (From IUPAC Gold …
How can molecularity be the order of the rate determining step?
Jan 11, 2014 · Molecularity, as per the collision theory, is defined only for elementary reactions. One of the things that define an elementary reaction is the fact that the entire transformation …
equilibrium - What is the molecularity of a reversible reaction ...
May 5, 2015 · I know that the definition of molecularity of a reaction is number of species reacting in an elementary step. But considering the theory of microscopic reversibility for elementary …
organic chemistry - Definition of Molecularity of a reaction ...
Mar 23, 2022 · Does molecularity depend on the total number of reacting entities, or the number of reacting entities at a particular site? I think molecularity will be defined wrt a specific site, in …
Confusion regarding order of reaction - Chemistry Stack Exchange
Jun 16, 2022 · It can be zero and even a fraction but molecularity cannot be zero or a non-integer. Its values are limited to 1,2 or 3. (ii) Order is applicable to elementary as well as complex …