Selective CO2 or CH4 adsorption of two anionic bcu-MOFs with …
A new bcu-MOF based upon a C2v-symmetrical [Cu4Cl(COO)4N8] cluster, [Cu4(Cl−)(L)4·4H2O]·(DMA+)·xDMF·yMeOH (SNNU-Bai66, SNNU-Bai = Shaanxi Normal University Bai's group), has been sucessfully synthesized.
Higher Symmetry Multinuclear Clusters of Metal–Organic …
Sep 18, 2018 · A new approach of finely tuning multinuclear clusters of metal–organic frameworks (MOFs) through symmetry-upgradingly isoreticular transformation was first presented and a bcu-type MOF, {[Cu4(μ4-O)...
A reticular chemistry guide for the design of periodic solids
Mar 10, 2021 · Reticular chemistry permits the geometry-guided pre-design of periodic frameworks, such as metal–organic frameworks (MOFs) and covalent organic frameworks (COFs), by connecting pre-selected...
Up–down approach for expanding the chemical space of metal
Sep 5, 2024 · Through ribbon representation and sophisticated analysis of the ligand angles, we suggest structure models and synthesize Zr 6 -based MOFs with bct (1) and scu (1) configurations. The up–down...
A 3D 8-connected bcu topological metal–organic framework built by ...
Jan 1, 2022 · A new 8-connected MOF based on [Cd 3 (COO) 6 (bmi) 4] nodes was prepared through a hydrothermal method and it was taken as a catalyst for the efficient and selective photodegradation of persistent dyes.
A porous metal organic framework with a bcu-type topology …
Crystal structure analysis showed that the complex crystallizes in the monoclinic space group P2 1 /c and has a decorated body centred cubic (bcu) topological net with 8-connected Cu3 cluster as node.
Reticular chemistry in the rational synthesis of functional zirconium ...
May 1, 2019 · In the past two decades, reticular chemistry has developed into a powerful tool for the design and synthesis of porous, crystalline framework materials. The discovery of the first hexanuclear, zirconium cluster-based MOF (i.e. UiO-66; fcu net) led to a vast library of functional Zr-MOFs with various properties. The versatile connectivity of ...
Two luminescent bcu-type metal-organic frameworks constructed …
Jun 1, 2015 · Tetranuclear cadmium clusters have been used as building units of Cd (II) MOF. Two Cd (II) MOFs with 8-connected bcu topology have been constructed. Luminescent properties and thermal stabilities were investigated.
Key Words: MOF, Co(II), Pyrimidinecarboxylate, Crystal structure, bcu Topology A secondary building unit (SBU)-based approach is an effective strategy for introducing design concepts in the synthesis
A 3D 8-connected bcu topological metal–organic framework built …
A new metal–organic framework (MOF), namely [Cd 3 (tp) 3 (bmi) 2] (SUSE-1, SUSE = Sichuan University of Science & Engineering) (H 2 tp = 1,4-dicarboxybenzene acid and bmi = 1,3-bis(2-methylimidazolyl)pentane), has been synthesized. It exhibits a typical 8-connected bcu-type network with [Cd 3 (COO) 6 (bmi) 4] nodes. SUSE-1