Mar 25, 2024 · In this regard, we selected the robust microporous aluminum 1,2,4,5-benzene tetracarboxylate framework MIL-120 (Al), due to its excellent CO 2 capture efficiency at relatively low pressure (1.9 mmol g −1 at 0.1 bar at 298 K), comparable to the best amine-free benchmark CO 2 adsorbents, as well as its potentially cheap production cost.

Jun 16, 2015 · The synthesis conditions of MIL-120 membranes supported by a-Al2O3 hollow ceramic fibers (HCFs) were studied systemically. The continuous and compact MIL-120 membranes were successfully synthesised by secondary growth with in situ seeding step.

Aug 17, 2023 · Here we report on a robust microporous aluminum tetracarboxylate framework, MIL-120 (Al)-AP, (MIL and AP refers to Materials from Institute Lavoisier and for Ambient Pressure synthesis, respectively), which possesses high CO2 uptake (1.9 mmol g-1 at 0.1 bar, 298 K) due to a favorable pore architecture combining high density of µ2-OH groups and s...

May 1, 2013 · A highly thermal stable metal–organic framework (MOF), MIL-120, was employed to incorporate low-cost nickel particles by simple impregnate method to obtain heterogeneous catalyst, Ni/MIL-120.

Mar 1, 2023 · A robust aluminum-based metal–organic framework (Al-MOF) MIL-120Al with 1D rhombic ultra-microporous was reported. The nonpolar porous walls composed of para-benzene rings with a comparable pore size to the kinetic diameter of methane allow it to exhibit a novel thermodynamic-kinetic synergistic separation of CH 4 /N 2 mixtures.

Oct 27, 2017 · The potential use of three metal–organic frameworks (MIL-53(Al), MIL-120(Al) and HKUST-1(Cu)) to adsorb iodine species (I 2 and ICH 3), which can be released during a severe nuclear accident, is investigated using periodic dispersion density functional theory for the first time. Competitive adsorption of iodine in the presence of water ...

Jan 25, 2023 · We evaluated the potential of MIL-120 (Al) for selective p X adsorption over other xylene isomers under single-component and multi-component liquid-phase conditions. Furthermore, we also tested the stability of MIL-120 (Al) under cyclic adsorption and desorption conditions and various pH conditions.

Breakthrough experiments reveal that MIL-120 can capture CO 2 from dry and wet flue gas with uptake capacities of 1.215 and 1.118 mmol g −1, respectively. Our work highlights the synthetic benefits of MIL-120 and elucidates its selective capture of CO 2 from wet flue gas.

Herein, we report an ultramicroporous metal–organic framework, namely, MIL-120 with a suitable pore size (5.4 Å × 4.7 Å), rich hydroxyl-decorated sites, and ultrahigh stability, which is capable of highly selective adsorption of xenon from krypton.

Jun 1, 2022 · MIL-120 (Al) is an aluminum-pyromellitate MOF with 1,2,4,5-benzenetetracarboxylate (BTEC) linkers [27]. Its thermal stability and porosity lead to several applications such as adsorption of small gas molecules including H 2, CH 4, CO 2 and noble gases as well as capture of iodine [28, 29].