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  1. VB-XPS价带谱计算价带位置 - 知乎 - 知乎专栏

    Feb 14, 2022 · 二、 VB XPS测得价带位置(Ev)根据价带X射线光电子能谱(VB XPS)的测试数据作图,将所得到图形在0 eV附近的直线部分外推至与水平的延长线相交,交点即为Ev。 如图8,根据ZnIn2S4以及O掺杂ZnIn2S4的VB XPS图谱,在0…

  2. How to analyze the XPS valence band spectra? | ResearchGate

    Jun 21, 2014 · The potentials of the conduction band (CB) and valence band (VB) of a semiconductor can be calculated using Mulliken electronegativity theory : ECB = X- Ec - 0.5 Eg (Eq.1) EVB = ECB + Eg (Eq.2)

  3. 浅谈能带结构分析基本方法—光谱及XPS、UPS结合法 - 知乎

    Aug 10, 2023 · 截线法是一种简易的求取半导体禁带宽度的方法,依据原理是半导体的吸收阈值λg和其禁带宽度Eg成反比,两者之间关系式如下: Eg (eV)=1240/λg (nm) 因此,可以通过求取λg来得到Eg。 从紫外可见漫反射谱图中可以得到材料在不同波长下的吸收。 对波长-吸收曲线求一次微分,之后在极值点做截线(斜率为极值点纵坐标数值),截线与横坐标交点即为λg。 代入上式可得材料的禁带宽度Eg。 方法二: Tauc plot法。 此方法由Tauc·Davis和Mott等人推导出, …

  4. Double-defect-induced polarization enhanced O - ScienceDirect

    Oct 5, 2022 · The chemical valence states and element information of the synthesized samples were examined using X-ray photoelectron spectroscopy (XPS). Fig. S2 shows the full spectrum of O V -BiOBr/Cu 2−x S, which confirms the presence of Bi, O, Br, Cu, and S elements.

  5. Direct extrapolation techniques on the energy band diagram of …

    Mar 1, 2021 · The CB and VB were determined by direct extrapolation from three different measurement techniques, namely XPS, Mott-Schottky and CV. Each technique exhibits almost similar values of CB and VB of BiVO 4 thin films.

  6. X‐ray photoelectron spectroscopy‐based valence band spectra of …

    Apr 16, 2022 · Thus, valence band (VB) spectra, obtained using X-ray photoelectron spectroscopy (XPS), are superpositions of the VB spectra of passive films and that of the metallic Ti substrate.

  7. XPS valence band spectra and theoretical calculations for ...

    Apr 21, 2006 · This paper reports on investigations of thiogermanate and thiosilicate crystals and glasses by means of XPS valence band spectra and theoretical calculations (FLAPW method).

  8. How to calculate valence band edge from XPS data

    After getting VB-XPS data plot it in origin software, interpolate the curve to the base line and this value will be VB value of your composite material. You can read following article and ask...

  9. How can I calculate valence band maxima of a semiconductor using XPS ...

    Jun 25, 2017 · You can measure the VBM directly by XPS. In general, we can get the information of valence band and core level by the PES(Photoemission spectroscopy) like XPS, UPS, ...

  10. Valence band structure and charge distribution in the layered ...

    Sep 23, 2021 · Thus, the current study involves the DFT calculation of the partial density of states (pDOS) and the experimental XPS valence band (VB) investigation.

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