
Reversible formation of coordination bonds in Sn-based metal …
May 25, 2021 · Here, we apply a metal-organic framework (MOF) chemistry between Sn-nodes and lithium active ligands to create two Sn-based MOFs comprising Sn 2 (dobdc) and Sn 2 (dobpdc) with extended...
Preparation of promising anode materials with Sn-MOF as …
Nov 25, 2020 · SnO@C, Sn/SnO@C and Sn@C were synthesized by One-step reduction method using Sn-MOF as both the precursor and the sacrificing template. SnO and Sn are embedded in a carbon matrix uniformly in the form of nanorods and nanospheres, respectively.
Sn(101) Derived from Metal–Organic Frameworks for Efficient ...
Jun 16, 2021 · A metal–organic framework (MOF) precursor Sn-MOF has been carbonized and then etched to successfully fabricate Sn (101)/SnO 2 /C composites with good control of the carbonization time and the concentration of hydrochloric acid.
Strengthening Sn-MOF with SiO2/GeO2 Nanoparticles for …
Jun 11, 2024 · Metal–organic frameworks (MOFs) based on tin (Sn) have shown great potential as materials for lithium storage, thanks to their ability to alleviate volume expansion due to the homogeneous distribution of Sn in a porous matrix framework.
Structural reconstruction of Sn-based metal–organic frameworks …
Mar 1, 2022 · Herein, a series of six N coordinated Sn-based metal-organic frameworks (Sn-N6-MOFs) are newly developed for electrochemical CO 2 reduction (CO 2 RR). 2% Sn-N6-MOF achieves the optimal catalytic performance with a formate Faradaic efficiency of ∼85% and a current density of 23 mA·cm −2 at −1.23 V vs. RHE.
Litchi-like Sn-MOF derived SnS2@SC composite as an advanced …
Mar 30, 2025 · In this study, a lyotropic Sn-MOF was synthesized using tin sulfate and terephthalic acid as the tin source and organic ligand. The lychee-like Sn-MOF was then utilized as a precursor to prepare a hollow porous SnS 2 @SC composite containing S-doped carbon through a hydrothermal method.
Innovative Microstructure and Morphology Engineering of MOF…
Feb 3, 2025 · Single-atom Sn-doped ZnO showing interdigitated lamellar morphology and porous structure is readily prepared based on mechanochemical synthesized Sn/Zn-metal-organic framework (MOF) precursor with we...
MOFs and their derivatives as Sn-based anode materials for lithium ...
Nov 5, 2021 · In this review, we mainly summarize the structural features, energy storage mechanism, and recent advances in the rational design and preparation of Sn-MOFs and MOF-derived Sn-based composites for LiB and SIB anodes, and current challenges and future directions for further development are discussed.
High-performance Sn-based metal-organic frameworks anode …
Dec 13, 2019 · Here, Sn-based MOFs anode materials with different morphologies are prepared by two different flexible and controllable methods, reflux method (named as reflux Sn-MOF), and hydrothermal method (named as hydrothermal Sn-MOF).
In-modified Sn-MOFs with high catalytic performance in formate ...
Aug 1, 2023 · Electrochemical reduction of carbon dioxide (CO2ER) has become an effective solution to relieve the energy crisis and tackle climate change. In this study, a series of tin-based organic frameworks modified by In (Sn-MOF/Inx) were successfully synthesized via a simple hydrothermal method and explored for high