Mar 1, 2023 · Hierarchically porous Zr-mofs (H-UiO-66-X) were synthesized through an in situ self-assembly template strategy. PMA/H-UiO-66–1 presented well-confined PMA in the …

Jul 6, 2012 · A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology. Zr and Hf based MOFs with enhanced pore …

Apr 26, 2023 · In this work, we report the concomitant synthesis of three topologically different MOFs based on the same M 6 O 4 (OH) 4 clusters (M = Zr or Hf) and methane-tetrakis (p …

Mar 10, 2021 · Reticular chemistry permits the geometry-guided pre-design of periodic frameworks, such as metal–organic frameworks (MOFs) and covalent organic frameworks …

Remarkably, reo-MOF-1 A exhibits permanent porosity (Brunauer−Emmett−Teller and Langmuir surface areas of 2104 and 2203 m2 g−1, respectively). Owing to these remarkable structural …

Aug 5, 2024 · We developed a method to synthesize unique reo-topology UiO-66 (reo-UiO-66), which features long-range-ordered missing-cluster defects. The growth of reo structures was …

Oct 27, 2022 · A Zr-based metal–organic framework with reo topology, denoted as Reo-MOF-1, was fabricated through a solvothermal method capable of efficiently removing the cationic MG …

Dec 9, 2022 · It is challenging but desirable to synthesize hierarchically porous MOFs (HP-MOFs) with well-defined topology. Herein, a series of HP-Zr-MOFs (H-UiO-66-X) with different …

May 1, 2019 · In this review, we summarize recent advances in the synthesis of zirconium cluster-based MOFs in the light of reticular chemistry design principles. Isoreticular tuning of MOF …

Jun 3, 2015 · Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in sorption and …