Oct 23, 2019 · Isoreticular metal–organic frameworks (IRMOFs) are a series of MOFs that own similar network topology. By simple substitution of organic linkers of IRMOF-1 (i.e., MOF-5), other IRMOFs can be obtained and have unique features such as large BET surface areas and high chemical stability.

May 11, 2021 · With Ir SAs as active centers, the defect-engineered MOF (e.g. activated NH 2 -UiO-66) particles can reduce CO 2 to HCOOH with an apparent quantum efficiency (AQE) of 2.51% at 420 nm on the...

Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability.

Feb 1, 2016 · Nanoscale IR-MOFs are synthesized by the improved coordination modulation method. Zinc acetate provides a zinc source, adjusts the pH, and acts as capping agent. IR-MOF films on ITO glass are formed by dipping-coating-secondary-growth. IR-MOF films have low k values, good mechanical strength and hydrophobicity.

Isoreticular metal-organic framework-3 (IRMOF-3), a porous coordination polymer, is an MOF material with the characteristics of a large specific surface area and adjustable pore size. Due to the existence of the active amino group (-NH 2) on the organic ligand, IRMOF-3 has more extensive research and application potential.

Oct 15, 2021 · In this review, we systematically describe all the synthetic methodologies of mixed-component isoreticular metal–organic frameworks, addressing the pore-chemistry along with suitable illustrative applications.

Nov 1, 2018 · In this work, we are utilizing a direct strategy for selective sensing of biomolecule and metal ion using IRMOF-3 that can enhance the utility of NMOFs. Glucose exists in human blood and its concentration level is one of the most representative characteristics for diagnosis.

Metal–organic frameworks (MOFs) are a family of hybrid porous materials that have attracted considerable research attention in recent years due to being promising candidates in a variety of significant applications, including sensing, catalysis, drug delivery, spintronics, photonics, and others [1, 2, 3, 4].

The fabricated IrO 2 @Ir-MOF-ppy electrode exhibits excellent OER activity with an overpotential of 207 mV, to achieve a current density of 10 mA cm −2 in 1 M KOH solution, outperforming most previously reported OER catalysts.

Nov 20, 2014 · We use 2D IR and other ultrafast IR methods to elucidate the timescales for ultrafast structural fluctuations and how they are influenced by a solvent filling the pores. The structural elasticity of metal–organic frameworks (MOFs) is a key property for their functionality.