
Transition-metal allyl complex - Wikipedia
Transition-metal allyl complexes are coordination complexes with allyl and its derivatives as ligands. Allyl is the radical with the connectivity CH 2 CHCH 2, although as a ligand it is …
Synthesis and isolation of highly reactive .eta.3-allyl alkyne ...
A Platinum Complex-Catalyzed Reaction of 3-Chloro-1,3-diene Monoepoxides with Carbon Nucleophiles Involving Nucleophilic Substitution at the Central Carbon Atom of the π-Allyl …
.eta.3-Allyl complexes of molybdenum: the preparation and …
Electron-Deficient Vanadium(III) Alkyl and Allyl Complexes with Amidinate Ancillary Ligands. Organometallics 1998 , 17 (18) , 4090-4095. https://doi.org/10.1021/om980431e
Transformation of .eta.3-allyl to .mu.-.eta.1,.eta.3-allylidene in ...
Generation of Dimethylsilylene and Allylidene Holmium Complexes from Trimethylsilylated Allyl Ligands. Journal of the American Chemical Society 2006, 128 (30) , 9622-9623. …
(Eta3-phenylallyl)(phosphanyloxazoline)palladium complexes: X …
Jul 15, 2002 · All possible (eta(3)-allyl)palladium complexes (1-4) of the ligand (4S)-[2-(2'-diphenylphosphanyl)phenyl]-4,5-dihydro-4-(2-propyl)-oxazole (L 1) and eta(3)-allyl ligands with …
Synthesis and Characterization of eta (3)-Allyl Palladium (II ...
Aug 1, 2011 · Spectroscopic studies suggest that sulfur donor ligands are bidentate, forming Pd-S-C-S and Pd-S-P-S palladacycles, an eta(3)-allyl group completing the coordination sphere.
(PDF) Photoreactivity of (.eta.3-allyl)palladium complexes in the ...
Depending on the medium, bis (p-chloro)bis (q3-ally1)dipalladium complexes react photochemically with organic halides to yield either halogen-exchanged complexes or …
eta(3)-Allyl carbonyl complexes of group 6 metals: Structural …
This review is focused on pi-allylic representatives of low-cost Group-6 metals bearing one or more carbonyl ligand, the coordination sphere being complemented with eta(5) …
New [Mo(eta3-allyl)(CO)2L3]+ complexes with monodentate or
Mar 7, 2005 · Cationic complexes [Mo (eta (3)-allyl) (CO)2L3]+ (L3 = either nitrogen-donor tridentate ligand or three monodentate ligands) were prepared in high yield and under mild …
An Unusual, Selective .eta.3-.eta.1 Allyl Isomerization in a Chiral ...
May 1, 1994 · Cyclopropanes by Nucleophilic Attack of Mono-and Diaryl-Substituted (?3-Allyl)palladium Complexes: Aryl Effect and Stereochemistry. Angewandte Chemie …