Apr 8, 2025 · Density functional theory (DFT) studies reveal the origin of the regioselectivity and stereoselectivity in Co-IPO-catalyzed hydroboration of aryl alkenes. Four insertion pathways …

Feb 25, 2025 · By employing a transposed NiH catalysis approach, this method facilitates the formation of key chiral nickel-amido intermediates, enabling asymmetric insertion into alkenes …

Oct 23, 2024 · Here we disclose an approach for the generation of alkyl carbanions via single-electron reduction of aryl alkenes, enabled by multi-photon photoredox catalysis. We …

Jun 14, 2022 · Herein, we report the catalyst generated in situ from a mixture of catalytic amounts of Ni (acac) 2 (as low as 0.005 mol%) and CsF, which is found highly active for Markovnikov …

Apr 26, 2024 · Herein, we report a general approach toward the aryl-alkylation of alkenes through a triple radical sorting mechanism. Over the course of the reaction, a high energy aryl radical, …

May 31, 2024 · Through mediation by a nickel-based catalyst, the three radicals are sorted into productive bond-forming pathways toward the efficient aryl-alkylation of alkenes. A wide range …

Jul 23, 2024 · Here, we report a visible-light-mediated dual catalysis strategy for the modular synthesis of highly functionalized and structurally diverse arylated chloroalkanes via the …

Here, without the use of any metal catalysts, a CH 3 CN-involved electrochemical borylation reaction is reported with alkenes and HBpin as substrates. The site-selectivity is realised to …

May 18, 2023 · Herein, by using a photocatalytic halogen-atom transfer strategy, we report a regioselective three-component 1,2-heterodiarylation of alkenes using readily accessible aryl …

Mar 29, 2024 · Specifically, we achieved the highly regioselective anti-Markovnikov hydrosilylation of aryl alkenes with a scandium alkyl complex Cp*Am tBu ScCH 2 SiMe 3 (Cp* = …