Zangerin, for instance, is Hado #78 — but it's used just once during the Thousand-Year Blood War arc. When Kyoraku Shunsui decides to challenge Lille Barro, one of Yhwach's Schutzstaffel ...

Just as Lille materialized in front of him, Shunsui performed Hado #78 Zangerin on the untouchable Quincy in an attempt to see if a powerful Kido attack could bypass his spatial intangibility.