"The novelty of this paper is that this is really the first time, to my knowledge, that someone has been able to get a carbocation shift that makes one of the mirror image products rather than the ...

Researchers step closer to mimicking nature's mastery of chemistry New approach to synthesis of chiral organic molecules Date: January 11, 2024 Source: ...

By tweaking its counter ion, classic carbocation inserts into C-H bonds. ... which forms multiple products depending upon a 1,2-hydride shift.

In the realm of reactivity, the vinyl carbocation is a beast so fleeting, so keen to combine or rearrange, that many have doubted that it can be tamed to create molecules in a stereoselective way ...

In nature, organic molecules are either left- or right-handed, but synthesizing molecules with a specific “handedness” in a lab is hard to do. Make a drug or enzyme with the wrong “handedness,” and it ...

Researchers step closer to mimicking nature’s mastery of chemistry New approach to synthesis of chiral organic molecules Peer-Reviewed Publication ...